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What are the fire - fighting measures for the chemical of CAS 78-40-0?

CAS 78 - 40 - 0 refers to Isopropylphenyl Diphenyl Phosphate (IPPP), a widely used chemical in various industries, especially as a flame retardant. As a supplier of CAS 78 - 40 - 0, it is crucial to understand the appropriate fire - fighting measures for this chemical to ensure safety during storage, transportation, and usage.

Chemical Properties of CAS 78 - 40 - 0

Isopropylphenyl Diphenyl Phosphate is an organophosphate ester. It has good thermal stability and flame - retardant properties, which makes it popular in applications such as plastics, rubber, and textiles. However, like many chemicals, it has specific fire - related characteristics that need to be considered.

Tritolyl PhosphateIsopropyled Triphenyl Phosphate 35

This chemical is a clear to pale - yellow liquid at room temperature. It has a relatively high boiling point and a low vapor pressure. In case of a fire, it may decompose under high - temperature conditions, releasing toxic and corrosive fumes, including phosphorus oxides and aromatic compounds.

Fire Hazards Associated with CAS 78 - 40 - 0

  1. Flammability: Although CAS 78 - 40 - 0 is not highly flammable under normal conditions, it can burn when exposed to high - energy ignition sources such as open flames, sparks, or intense heat. Once ignited, it can sustain combustion, especially in the presence of oxygen.
  2. Toxic Fumes: During combustion, CAS 78 - 40 - 0 decomposes to produce toxic fumes. Phosphorus oxides can cause irritation to the respiratory system, eyes, and skin. Aromatic compounds released may also have carcinogenic and mutagenic properties, posing serious health risks to those exposed.
  3. Reactivity: In some cases, if CAS 78 - 40 - 0 comes into contact with strong oxidizing agents during a fire, it may react violently, increasing the intensity of the fire and the potential for explosion.

Fire - Fighting Measures

Extinguishing Agents

  1. Dry Chemical Extinguishers: Dry chemical extinguishers, such as those containing ABC dry chemicals (ammonium phosphate - based), are effective for extinguishing fires involving CAS 78 - 40 - 0. These extinguishers work by interrupting the chemical reaction of the fire, smothering the flames, and preventing re - ignition. The dry powder can also absorb heat from the fire, helping to cool the burning material.
  2. Carbon Dioxide (CO₂) Extinguishers: CO₂ extinguishers are suitable for small fires involving CAS 78 - 40 - 0. They work by displacing oxygen from the fire area, suppressing the combustion process. CO₂ is non - conductive and leaves no residue, which is beneficial for protecting electrical equipment and preventing damage to surrounding areas. However, CO₂ extinguishers have a limited range and discharge time, so they are more suitable for initial fire suppression.
  3. Foam Extinguishers: Aqueous film - forming foam (AFFF) or protein - based foam extinguishers can be used for larger fires involving CAS 78 - 40 - 0. Foam extinguishers work by creating a layer of foam on the surface of the burning liquid, preventing the release of flammable vapors and smothering the fire. The foam also cools the burning material, reducing the risk of re - ignition.

Fire - Fighting Procedures

  1. Evacuation and Isolation: In case of a fire, the first step is to evacuate all non - essential personnel from the area. Establish a safe perimeter around the fire site to prevent unauthorized access. Isolate the fire from other combustible materials and sources of ignition to prevent the spread of the fire.
  2. Personal Protective Equipment (PPE): Firefighters and those involved in fire - fighting operations should wear appropriate PPE. This includes fire - resistant clothing, self - contained breathing apparatus (SCBA) to protect against toxic fumes, and protective gloves and boots. PPE should be inspected regularly to ensure its effectiveness.
  3. Fire - Fighting Strategy: Approach the fire from an upwind direction to avoid exposure to toxic fumes. Use the appropriate extinguishing agent based on the size and intensity of the fire. Start by aiming at the base of the flames and work your way up. For large fires, multiple extinguishers or a combination of extinguishing methods may be required.
  4. Monitoring and Ventilation: After the fire is extinguished, continue to monitor the area for any signs of re - ignition. Ventilate the area to remove any remaining toxic fumes. Use fans or open windows and doors to ensure proper air circulation.

Storage and Handling Precautions to Prevent Fires

  1. Storage Conditions: Store CAS 78 - 40 - 0 in a cool, dry, and well - ventilated area away from sources of heat, open flames, and strong oxidizing agents. Keep the chemical in tightly sealed containers to prevent the release of vapors. Use storage cabinets or rooms that are designed to contain spills and prevent the spread of fire.
  2. Handling Procedures: When handling CAS 78 - 40 - 0, follow proper safety procedures. Use appropriate equipment, such as pumps and hoses, to transfer the chemical. Avoid spills and leaks, and clean up any spills immediately using absorbent materials. Ground and bond containers during transfer to prevent static electricity buildup, which can be a potential ignition source.

Comparison with Other Flame Retardants

There are several other flame retardants in the market, such as Isopropyled Triphenyl Phosphate 35, Tritolyl Phosphate, and Tetraphenyl Resorcinol Bis(diphenylphosphate). Each of these flame retardants has its own fire - fighting measures based on their chemical properties.

Isopropyled Triphenyl Phosphate 35 is also an organophosphate - based flame retardant. Similar to CAS 78 - 40 - 0, it may release toxic fumes during combustion. However, its flammability and reactivity may differ slightly, so the choice of extinguishing agent may need to be adjusted accordingly.

Tritolyl Phosphate is another commonly used flame retardant. It has different physical and chemical properties compared to CAS 78 - 40 - 0. For example, it may have a different boiling point and solubility, which can affect its behavior in a fire. The fire - fighting measures for Tritolyl Phosphate may involve similar extinguishing agents but with different application techniques.

Tetraphenyl Resorcinol Bis(diphenylphosphate) is a high - performance flame retardant. It is more thermally stable than some other flame retardants, but in case of a fire, it still requires appropriate fire - fighting measures. The toxic fumes released during its combustion may also be different from those of CAS 78 - 40 - 0, so specific precautions need to be taken.

Conclusion

As a supplier of CAS 78 - 40 - 0, understanding the fire - fighting measures for this chemical is essential for ensuring the safety of our customers and the environment. By following the appropriate fire - fighting procedures, using the right extinguishing agents, and taking storage and handling precautions, we can minimize the risks associated with fires involving CAS 78 - 40 - 0.

If you are interested in purchasing CAS 78 - 40 - 0 or have any questions about its safety and usage, please feel free to contact us for further discussions. We are committed to providing high - quality products and comprehensive technical support.

References

  1. "Handbook of Fire - Fighting Chemicals"
  2. Safety Data Sheet (SDS) for Isopropylphenyl Diphenyl Phosphate (CAS 78 - 40 - 0)
  3. Industry standards and guidelines for the storage and handling of organophosphate esters.

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